Scientists at the Fraunhofer Institute for Material and Beam Technology IWS in Dresden have developed a new design that increases the charge cycles of lithium-sulfur batteries by a factor of seven. "During previous tests, the batteries scarcely crossed the 200-cycle mark. By means of a special combination of anode and cathode material, we have now managed to extend the lifespan of lithium-sulfur button cells to 1,400 cycles," says Dr. Holger Althues, head of the Chemical Surface Technology group at IWS, who is delighted with his team's breakthrough.
The anode of the team's prototype is not made from the usual metallic lithium, but from a silicon-carbon compound instead. This compound is significantly more stable, as it changes less during each charging process than metallic lithium. The more the structure of the anode changes, the more it interacts with the liquid electrolyte, which is situated between the anode and the cathode and carries the lithium-ions. This process causes the liquid to break down into gas and solids and the alkaline battery to dry out. "In extreme cases, the anode "grows" to reach the cathode, creating a short circuit and causing the battery to stop working altogether," explains Althues.
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